Module also offered within study programmes:
Code Study programme
CTC-2-311-TC-s Chemical Technology (Technologia ceramiki i materiałów ogniotrwałych) - full-time studies second-cycle studies
CTC-2-407-TC-s Chemical Technology (Technologia ceramiki i materiałów ogniotrwałych) - full-time studies second-cycle studies
CCB-2-308-s Chemistry of Building Materials - full-time studies second-cycle studies
CTC-2-308-TS-s Chemical Technology (Technologia szkła i powłok amorficznych) - full-time studies second-cycle studies
CTC-2-309-TM-s Chemical Technology (Technologia materiałów budowlanych) - full-time studies second-cycle studies
CIM-2-307-MN-s Materials Science (Mikro i nanotechnologie materiałowe) - full-time studies second-cycle studies
CIM-2-306-MF-s Materials Science (Materiały funkcjonalne) - full-time studies second-cycle studies
CIM-2-307-FM-s Materials Science (Functional Materials) - full-time studies second-cycle studies
CCE-2-315-WC-s Ceramics (Wzornictwo ceramiki i szkła) - full-time studies second-cycle studies
CCE-2-315-CT-s Ceramics (Ceramika techniczna i konstrukcyjna) - full-time studies second-cycle studies
CCE-2-315-MK-s Ceramics (Materiały dla konserwacji i rewitalizacji) - full-time studies second-cycle studies
CIM-1-044-s Materials Science - full-time studies first-cycle studies
CIM-2-306-BK-s Materials Science (Biomateriały i kompozyty) - full-time studies second-cycle studies
CTC-2-007-TC-s Chemical Technology (Technologia ceramiki i materiałów ogniotrwałych) - full-time studies second-cycle studies
CTC-2-043-AK-s Chemical Technology (Analityka i kontrola jakości) - full-time studies second-cycle studies
CIM-2-009-MN-s Materials Science (Mikro i nanotechnologie materiałowe) - full-time studies second-cycle studies
CIM-2-009-BK-s Materials Science (Biomateriały i kompozyty) - full-time studies second-cycle studies
CIM-2-019-MF-s Materials Science (Materiały funkcjonalne) - full-time studies second-cycle studies
CCB-1-019-s Chemistry of Building Materials - full-time studies first-cycle studies
CTC-2-009-AK-s Chemical Technology (Analityka i kontrola jakości) - full-time studies second-cycle studies
CCE-1-009-s Ceramics - full-time studies first-cycle studies
CTC-1-056-s Chemical Technology - full-time studies first-cycle studies
General information:
Name:
Solid state chemistry
Course of study:
2015/2016
Code:
CTC-2-309-TM-s
Faculty of:
Materials Science and Ceramics
Study level:
Second-cycle studies
Specialty:
Technologia materiałów budowlanych
Field of study:
Chemical Technology
Semester:
3
Profile of education:
Academic (A)
Lecture language:
English
Form and type of study:
Full-time studies
Course homepage:
 
Responsible teacher:
prof. dr hab. inż. Danielewski Marek (daniel@agh.edu.pl)
Academic teachers:
prof. dr hab. inż. Danielewski Marek (daniel@agh.edu.pl)
dr inż. Kucza Witold (witek@agh.edu.pl)
dr hab. Wierzba Bartłomiej (bwierzba@agh.edu.pl)
Module summary

Description of learning outcomes for module
MLO code Student after module completion has the knowledge/ knows how to/is able to Connections with FLO Method of learning outcomes verification (form of completion)
Social competence
M_K001 Student rozumie potrzebę dokształcanie się w zakresie chemii ciała stałego, która ułatwi mu podnoszenie swoich kwalifikacji zawodowych Activity during classes,
Participation in a discussion
Skills
M_U001 Student potrafi obliczać stężenia defektów i stałe szybkości reakcji Activity during classes,
Test,
Presentation,
Participation in a discussion
Knowledge
M_W001 Student zna zasady obliczania prężności dysocjacyjnych, stężeń defektów i stałcyh szybkości reakcji heterogenicznych Activity during classes,
Test,
Presentation,
Participation in a discussion
M_W002 Student ma wiedzę z zakresu metod modelowania przpływów masy i ładunku. Activity during classes,
Test,
Presentation,
Participation in a discussion
FLO matrix in relation to forms of classes
MLO code Student after module completion has the knowledge/ knows how to/is able to Form of classes
Lecture
Audit. classes
Lab. classes
Project classes
Conv. seminar
Seminar classes
Pract. classes
Zaj. terenowe
Zaj. warsztatowe
Others
E-learning
Social competence
M_K001 Student rozumie potrzebę dokształcanie się w zakresie chemii ciała stałego, która ułatwi mu podnoszenie swoich kwalifikacji zawodowych - - - - - + - - - - -
Skills
M_U001 Student potrafi obliczać stężenia defektów i stałe szybkości reakcji - - - - - + - - - - -
Knowledge
M_W001 Student zna zasady obliczania prężności dysocjacyjnych, stężeń defektów i stałcyh szybkości reakcji heterogenicznych - - - - - + - - - - -
M_W002 Student ma wiedzę z zakresu metod modelowania przpływów masy i ładunku. - - - - - + - - - - -
Module content
Seminar classes:

Fundamentals of solid-state chemistry and reactivity of solids. The point defects chemistry, in stoichio-metric and non-stoichiometric compounds. The mass and charge transport in solids, the bi-velocity method. Various mechanisms and models for diffusion in different classes of materials. The rate of heterogeneous solid-solid, solid-liquid and gas solid reactions.
Fundamental concepts of solid state chemistry: Arrhenius, Einstein, Wagner, Schottky, Onsager, Darken, Schrödinger, DFT.
Thermodynamics of solids; canonical equation of thermodynamics, Gibbs and Gibbs-Duhemè equations, dissociation pressure, phase diagrams.
Point defect chemistry; Kröger-Vink notation, basic rules, doping, oxides with complex defect structure. Applications; color centers, semiconductors, SOFC and sensors. Complex defects, experimental methods and quasi-stationary processes.
Mechanisms of diffusion; self-diffusion, Fick’s laws, Nernst-Plank flux, Nernst-Einstein relation.
Diffusion equation: discrete and continuous forms, derivation, chemical diffusion, thermodynamic factor, diffusion potential, nonlinear diffusion and constitutive flux formulas. The mass conservation law.
Chemicalinterdiffusion in solid solutions: Darken’s model, Kirkendall shift, intrinsic diffusivities and interdiffusion coefficient, segregation and up-hill diffusion, bi-velocity method.
Heterogeneous reactions, reactive diffusion; the Wagner’s theory of heterogeneous reaction, bi-velocity method, thin films.
Solid-state electrochemistry, Nernst-Planck-Poisson problem.
Reactivity of solids; multicomponent and multiphase systems, soldering, diffusion bonding.
Nano materials, grain boundary diffusion, Fischer model, reactions in thin films.
Equation of state, reactions in solids at high pressures, sedimentation.
Waves in solids, energy conservation and entropy production in open systems, unsolved problems.

Student workload (ECTS credits balance)
Student activity form Student workload
Summary student workload 84 h
Module ECTS credits 3 ECTS
Contact hours 7 h
Examination or Final test 4 h
Realization of independently performed tasks 20 h
Preparation for classes 10 h
Participation in seminar classes 28 h
Preparation of a report, presentation, written work, etc. 15 h
Additional information
Method of calculating the final grade:

OK=0,4 P + 0,6 K,
gdzie: P-ocena z prezentacji
K-ocena z kolokwium

Suma uzyskanych punktów przeliczana jest na ocenę końcowa zgodnie z regulaminem studiów AGH.

Prerequisites and additional requirements:

Znajomośc podstaw chemii ogólnej i chemii fizycznej

Recommended literature and teaching resources:

Literatura podstawowa/References (Basic):

R. W. Balluffi, S. M. Allen, W. C. Carter, R. A. Kemper, Kinetics of Materials, (Hoboken: J. Wiley & Sons; 2005).
R. J. Borg i G. J. Dienes, The Physical Chemistry of Solids (Academic Press NY, London 1992).
K-N Tu, J. W. Mayer, L. C. Feldman, Electronic Thin Film Science for Electrical Engineers and Materials Scientists

Literatura dodatkowa/References (Additional):

H. Schmalzried, Reakcje w stanie stałym (PWN, Warszawa 1978) also in english.
M. Danielewski and B.Wierzba, „Thermodynamically consistent bi-velocity mass transport phenomenology”, Acta Materialia 58 (2010) 6717–6727.

Scientific publications of module course instructors related to the topic of the module:

Additional scientific publications not specified

Additional information:

None