Module also offered within study programmes:
General information:
Name:
Chemistry of organosilicon compounds
Course of study:
2018/2019
Code:
CTC-1-511-s
Faculty of:
Materials Science and Ceramics
Study level:
First-cycle studies
Specialty:
-
Field of study:
Chemical Technology
Semester:
5
Profile of education:
Academic (A)
Lecture language:
English
Form and type of study:
Full-time studies
Course homepage:
 
Responsible teacher:
prof. dr hab. inż. Hasik Magdalena (mhasik@agh.edu.pl)
Academic teachers:
prof. dr hab. inż. Hasik Magdalena (mhasik@agh.edu.pl)
Module summary

During the course students get acquainted with the main classes of organosilicon compounds. The course can be treated as the one expanding the knowledge of chemistry acquired during previous studies.

Description of learning outcomes for module
MLO code Student after module completion has the knowledge/ knows how to/is able to Connections with FLO Method of learning outcomes verification (form of completion)
Social competence
M_K001 is aware of the consequences of application of organosilicon compounds in everyday life and in chemical technology TC1A_K01, TC1A_K12, TC1A_K09 Activity during classes
Skills
M_U002 is able to select an organosilicon compound for a given application TC1A_U12, TC1A_U05, TC1A_U02 Presentation
M_U003 can give a proper name to an organosilicon compound, can identify it based on IR and NMR spectra TC1A_U01 Presentation
Knowledge
M_W003 is familiar with the main classes of organosilicon compounds, knows how to name them TC1A_W01 Activity during classes
M_W004 knows the methods of preparation of various organosilicon compounds, knows their physical and chemical properties TC1A_W01 Presentation
FLO matrix in relation to forms of classes
MLO code Student after module completion has the knowledge/ knows how to/is able to Form of classes
Lecture
Audit. classes
Lab. classes
Project classes
Conv. seminar
Seminar classes
Pract. classes
Zaj. terenowe
Zaj. warsztatowe
Others
E-learning
Social competence
M_K001 is aware of the consequences of application of organosilicon compounds in everyday life and in chemical technology - - - - - + - - - - -
Skills
M_U002 is able to select an organosilicon compound for a given application - - - - - + - - - - -
M_U003 can give a proper name to an organosilicon compound, can identify it based on IR and NMR spectra - - - - - + - - - - -
Knowledge
M_W003 is familiar with the main classes of organosilicon compounds, knows how to name them - - - - - + - - - - -
M_W004 knows the methods of preparation of various organosilicon compounds, knows their physical and chemical properties - - - - - + - - - - -
Module content
Seminar classes:

Topics of the seminar classes include:

1. Silicon – its atomic properties, bonds formed with other elements in the Periodic Table.
2. Main organosilicon compounds and their nomenclature. General synthetic routes to organosilicon compounds.
3. Principles of IR spectroscopy. Characterization of organosilicon compounds by IR spectroscopy.
4. Principles of NMR spectroscopy. Characterization of organosilicon compounds by NMR spectroscopy.
5. Compounds containing Si-H bonds (organohydrosilanes, organohydrosiloxanes). Hydrosilylation.
6. Organosilanes and polyorganosilanes – chemical structure, synthesis, properties and applications.
7. Ladder and polyhedral oligomeric silsesquioxanes.
8. Organosilanes and polyorganosilanes – chemical structure, synthesis, properties and applications.
9. Carbo- and Polycarbosilanes – chemical structure, synthesis, properties and applications.
10. Silane coupling agents.
11. Organosilicon compounds in biological environment.

Student workload (ECTS credits balance)
Student activity form Student workload
Summary student workload 75 h
Module ECTS credits 3 ECTS
Participation in seminar classes 30 h
Preparation for classes 15 h
Preparation of a report, presentation, written work, etc. 15 h
Realization of independently performed tasks 15 h
Additional information
Method of calculating the final grade:

Final grade is based on activity during the classes, homework and presentations on selected topics in organosilicon chemistry prepared by the student.

Prerequisites and additional requirements:

During the course, each student has to make an oral presentation on a selected topic in organosilicon chemistry.

Recommended literature and teaching resources:

1. M.A. Brook, “Silicon in Organic, Organometallic and Polymer Chemistry”, Wiley, NY 2000
2. R.G. Jones, W. Ando, J. Chojnowski (editors) “Silicon-containing polymers”, Kluwer Academic Press, Dordrecht 2000
3. scientific papers devoted to organosillicon compounds

Scientific publications of module course instructors related to the topic of the module:

1. A. Nyczyk, C. Paluszkiewicz, A. Pyda, M. Hasik “Preceramic polysiloxane networks obtained by hydrosilylation of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane”, Spectrochimica Acta 79 (2011) 801-808.
2. A. Nyczyk, C. Paluszkiewicz, M. Hasik, M. Cypryk, P. Pospiech “Cross-linking of linear vinylpolysiloxanes by hydrosilylation – FTIR spectroscopic studies”, Vibrational Spectroscopy 59 (2012) 1-8.
3. M. Hasik, M. Wójcik-Bania, A. Nyczyk, T. Gumuła “Polysiloxane-POSS systems as precursors to SiCO ceramics”, Reactive & Functional Polymers 73 (2013) 779-788.
4. A. Nyczyk-Malinowska, E. Dryzek, M. Hasik, J. Dryzek “Various types of polysiloxanes studied by positron annihilation lifetime spectroscopy” Journal of Molecular Structure 1065-1066 (2014) 254-261.
5. A. Nyczyk-Malinowska, M. Wójcik-Bania, T. Gumuła, M. Hasik, M. Cypryk, Z. Olejniczak “New precursors to SiCO ceramics derived from linear poly(vinylsiloxanes) of regular chain composition” Journal of the European Ceramic Society 34 (2014) 889-902.
6. M. Wójcik-Bania, J. Olejarka, T. Gumuła, A. Łącz, M. Hasik “Influence of metallic palladium on thermal properties of polysiloxane networks” Polymer Degradation and Stability 109 (2014) 249-260.
7. M. Wójcik-Bania, A. Krowiak, J. Strzezik, M. Hasik “Pt supported on cross-linked poly(vinylsiloxanes) and SiCO ceramics – new materials for catalytic applications” Materials & Design 96 (2016) 171-179.
8. M. Wójcik-Bania, A. Łącz, A. Nyczyk-Malinowska, M. Hasik “Poly(methylhydrosiloxane) networks of different structure and content of Si-H groups: Physicochemical properties and transformation into silicon oxycarbide ceramics”, Polymer 130 (2017) 170-181.
9. J. Olejarka, A. Łącz, Z. Olejniczak, M. Hasik “Non-porous and porous materials prepared by cross-linking of polyhydrothylsiloxane with silazane compounds”, European Polymer Journal 97 (2018) 150-164.

Additional information:

None