Module also offered within study programmes:
Code Study programme
CIM-2-318-MF-s Materials Science (Materiały funkcjonalne) - full-time studies second-cycle studies
CIM-2-318-MN-s Materials Science (Zaawansowane Materiały Ceramiczne) - full-time studies second-cycle studies
CCE-2-318-WC-s Ceramics (Wzornictwo ceramiki i szkła) - full-time studies second-cycle studies
CIM-2-318-BK-s Materials Science (Biomateriały i kompozyty) - full-time studies second-cycle studies
CTC-2-318-TC-s Chemical Technology (Technologia ceramiki i materiałów ogniotrwałych) - full-time studies second-cycle studies
CTC-2-318-TM-s Chemical Technology (Technologia materiałów budowlanych) - full-time studies second-cycle studies
CTC-2-318-TS-s Chemical Technology (Technologia szkła i powłok amorficznych) - full-time studies second-cycle studies
CTC-2-329-AK-s Chemical Technology (Analityka i kontrola jakości) - full-time studies second-cycle studies
CIM-1-006-s Materials Science - full-time studies first-cycle studies
CIM-2-318-FM-s Materials Science (Functional Materials) - full-time studies second-cycle studies
CTC-2-418-AK-s Chemical Technology (Analityka i kontrola jakości) - full-time studies second-cycle studies
CCE-2-318-MK-s Ceramics (Materiały dla konserwacji i rewitalizacji) - full-time studies second-cycle studies
CCE-2-318-CT-s Ceramics (Ceramika techniczna i konstrukcyjna) - full-time studies second-cycle studies
CIM-2-418-MF-s Materials Science (Materiały funkcjonalne) - full-time studies second-cycle studies
CCE-1-002-s Ceramics - full-time studies first-cycle studies
General information:
Name:
Physical Chemistry of Surfaces and Surface Analytical Techniques
Course of study:
2018/2019
Code:
CIM-2-318-BK-s
Faculty of:
Materials Science and Ceramics
Study level:
Second-cycle studies
Specialty:
Biomateriały i kompozyty
Field of study:
Materials Science
Semester:
3
Profile of education:
Academic (A)
Lecture language:
English
Form and type of study:
Full-time studies
Course homepage:
 
Responsible teacher:
prof. nadzw. dr hab. inż. Jedliński Jerzy (jedlinsk@agh.edu.pl)
Academic teachers:
prof. nadzw. dr hab. inż. Jedliński Jerzy (jedlinsk@agh.edu.pl)
dr hab. inż. Nocuń Marek (nocun@agh.edu.pl)
Module summary

Part I focuses on description of surfaces (physical and chemical), surface processes and surface-affected properties of materials, while part II deals with surface analytical methods

Description of learning outcomes for module
MLO code Student after module completion has the knowledge/ knows how to/is able to Connections with FLO Method of learning outcomes verification (form of completion)
Social competence
M_K001 Potrafi pracować w zespole IM2A_K02
Skills
M_U002 Potrafi scharakteryzować metody badania zjawisk i procesów zachodzących na powierzchni zewnętrznej i powierzchniach granicznych IM2A_U06, IM2A_U01
M_U003 Potrafi opisać procesy zachodzące na powierzchni zewnętrznej materiałów oraz na powierzchniach granicznych IM2A_U05, IM2A_U02, IM2A_U09, IM2A_U01, IM2A_U11
Knowledge
M_W001 Zna najczęściej zachodzące zjawiska i procesy na powierzchni zewnętrznej oraz na powierzchnuach granicznych IM2A_W03
M_W002 Zna metody badania powierzchni zewnętrznej oraz powierzchni granicznych IM2A_W02, IM2A_W08
M_W003 Ma wiedzę w zakresie fizykochemicznego opisu procesów i zjawisk zachodzących na powierzchni zewnętrznej i powierzchniach granicznych i ich związku z właściwościami materiałów IM2A_W03, IM2A_W02, IM2A_W09
M_W004 Kształtuje odpowiedzialne podejście do wykonywanych zadań oraz rozumie potrzebę ciągłego aktualizowania swoich: wiedzy i umiejętności IM2A_K03, IM2A_K08, IM2A_K02, IM2A_K06
FLO matrix in relation to forms of classes
MLO code Student after module completion has the knowledge/ knows how to/is able to Form of classes
Lecture
Audit. classes
Lab. classes
Project classes
Conv. seminar
Seminar classes
Pract. classes
Zaj. terenowe
Zaj. warsztatowe
Others
E-learning
Social competence
M_K001 Potrafi pracować w zespole - - - - - + - - - - -
Skills
M_U002 Potrafi scharakteryzować metody badania zjawisk i procesów zachodzących na powierzchni zewnętrznej i powierzchniach granicznych - - - - - + - - - - -
M_U003 Potrafi opisać procesy zachodzące na powierzchni zewnętrznej materiałów oraz na powierzchniach granicznych - - - - - + - - - - -
Knowledge
M_W001 Zna najczęściej zachodzące zjawiska i procesy na powierzchni zewnętrznej oraz na powierzchnuach granicznych - - - - - + - - - - -
M_W002 Zna metody badania powierzchni zewnętrznej oraz powierzchni granicznych - - - - - + - - - - -
M_W003 Ma wiedzę w zakresie fizykochemicznego opisu procesów i zjawisk zachodzących na powierzchni zewnętrznej i powierzchniach granicznych i ich związku z właściwościami materiałów - - - - - + - - - - -
M_W004 Kształtuje odpowiedzialne podejście do wykonywanych zadań oraz rozumie potrzebę ciągłego aktualizowania swoich: wiedzy i umiejętności - - - - - + - - - - -
Module content
Seminar classes:
Physical chemistry of surfaces and surface analytical techniques

Content is divided into two following parts

Part I: Physical chemistry of surfaces:
1. Ideal and real surfaces
2. Thermodynamics of surfaces
3. The structure of surfaces.
4. Crystal thermodynamics (with relevance to surface)
5. Molecular and mechanical description of surfaces
6. Surface dynamics
7. Electrical properties of surfaces
8. Surface processes and properties (clean surface structure, reconstruction, solid-gas interface-general considerations, adsorption, catalysis by surfaces, mechanical properties of surfaces, friction, lubrication and adhesion, wetting, floating, detergency, growth of surface layers, catalytic growth of nanotubes and nanowires, structure formation by etching, various processes on solid surfaces, colloids and relevant processes)

Part II: Surface analytical techniques
9. Concept of selvedge
10. General description of the concept of surface analysis and approach
9. Interaction of the particles/radiation with matter: application to surface investigation
10. Parameters of surface methods
11. Electron spectroscopies: XPS (X-ray Photoelectron Spectroscopy), AES (Auger Electron Spectroscopy, SAM (Scanning Electron Microscopy)
12. Scattered Ion Mass Spectrometry of light ions: RBS (Rutherford Backscattering Spectrometry), ISS (Ion Scattered Spectrometry)
13. Ion-Beam Mass Spectrometry – emitted ions: SIMS (Secondary Ion Mass Spectrometry), SNMS (Sputtered Neutrals Mass Spectrometry)
14. Scanning Probe Microscopy (SPM): STM (Scanning Tunnelling Microscopy), AFM (Atomic Force Microscopy), other
15. Electron microscopies: SEM (Scanning Electron Microscopy), TEM (Transmission Electron Microscopy), Sample preparation methods to electron microscopy studies (FIB, ion-beam thinning, …)
16. Glow Discharge Optical Emission Spectroscopy (GDOES)
27. Grazing Incidence X-Ray Methods

Student workload (ECTS credits balance)
Student activity form Student workload
Summary student workload 77 h
Module ECTS credits 3 ECTS
Participation in seminar classes 30 h
Examination or Final test 2 h
Realization of independently performed tasks 30 h
Preparation for classes 15 h
Additional information
Method of calculating the final grade:

Prezentacja/Presentation (50%) + Kolokwium końcowe/Final test (50%)

Prerequisites and additional requirements:

1. English skills: general as well as field-related (scientific and technological)
2. Physics and chemistry at intermediate level (mainly solid state physics and chemistry)

Recommended literature and teaching resources:

K.W. Kolasinski, Surface Science, 2nd Edition, Wiley & Sons, 2008
G.A. Somorjai, Introduction to Surface Chemistry and Catalysis, Wiley & Sons, 1994 or later
A.W. Adamson, A.P. Gast, Physical Chemistry of Surfaces 6th Edition, Wiley & Sons, 1997 or later
J.A. Venables, Introduction to surface and thin film processes, Cambridge University Press, 2000
G. Friedbacher, H. Bubert (Ed.), Surface and Thin Films Analysis, Wiley-VCH Verlag GmbH KGaA,Weinheim, 2011
S. Myhra, J.C. Rivere, Characterization of Nanostructures, CRC Press, Taylor & Francis Group, Bova Raton, 2012
D.J. O’Connor, B.A. Sexton, R.St.C. Smart, Surface Analysis Methods in Materials Science, Springer, Berlin-Heidelberg, 2nd Ed., 2003
Y. Leng, Materials Characterization, Wiley & Sons (Asia), Singapore, 2008
D. Brandon, W.D. Kaplan, Microstructural Characterization of Materials, 2nd Edition, John Wiley & Sons Ltd., Chichester, 2008
D.P. Woodruff, Modern Techniques of Surface Science, 3rd edition, Cambridge University Press, 2016

Scientific publications of module course instructors related to the topic of the module:

1. J. Jedliński, J.L. Grosseau Poussard, G. Smoła, G. Bonnet, M. Nocuń, K. Kowalski, and J. Dąbek, “The effect of alloyed and/or implanted yttrium on the mechanism of the scale development on β-NiAl at 1100oC”, Materials at High Temperatures, 29 (2), 59-69 (2012)
2. J. Jedlinski, J.L. Grosseau-Poussard, M. Nocuń, G. Smoła, K. Kowalski, J. Dąbek, A. Rakowska, G. Bonnet
“The Early Stages of the Scale Growth on FeCrAl(RE)-Type Alumina Formers”
Materials Science Forum, 696, 70-75 (2011)
3. H.J. Choi, J. Jedlinski, B. Yao, Y.H. Sohn
“Transmission electron microscopy observations on the phase composition and microstructure of the oxidation scale grown on as-polished and yttrium-implanted β-NiAl”
Surface & Coatings Technology, 205 (2010) 1206–1210
4. J. Jedlinski
“Application of 18O2 Exposure–Based Approach to Study the Failure Mechanisms of Oxide Scales on Alumina Formers”
Materials Science Forum, 513 (2006) 149-164
5. J. Jedliński, A. Bernasik, K. Kowalski and M. Nocun
“On the Application of SIMS to Study the Oxidation Behaviour of Alumina Formers”
Materials at High Temperatures, 22 (2005) 505-520
6. J. Jedliński
“Local and Microstructure-related Effects Affecting the High Temperature Oxidation of Alumina Formers: A Brief Survey”
Materials at High Temperatures, 22 (2005) 485-496
7. M. Nocuń, J. Jedliński, E. Leja
“Spectroscopic studies of hybrid glasses based on TEOS-cyclosiloxane systems”
Proc. XXth International Congress on Glass, Kyoto, 27.09-1.10.2004, Paper : P-11-031
8. J. Jedliński, M. Konopka, M. Goebel, A. Glazkov, A. Bernasik, M. Nocun, J. Camra, G. Borchardt
“The Use of XPS and SIMS in Studying the Early Oxidation Stages of FeCrAl-Based High Temperature Alloys”
Proc. 7th European Conference on Applications of Surface and Interface Analysis, ECASIA’97, Göteborg, 1997, Ed. I. Olefjord, L. Nyborg, D. Briggs, J. Wiley & Sons, Chichester, 1997, p. 259 – 262
9. K. Kowalski, A. Bernasik, A. Sadowski, J. Janowski, M. Radecka, J. Jedliński
“SIMS Investigation of Titanium Diffusion in Yttria Stabilised Zirconia”
Proc. 7th European Conference on Applications of Surface and Interface Analysis, ECASIA’97, Göteborg, 1997, Ed. I. Olefjord, L. Nyborg, D. Briggs, J. Wiley & Sons, Chichester, 1997, p. 259 – 262
10. A. Bernasik, K. Kowalski, A. Sadowski, J. Janowski, J. Jedliński
“XPS Study of the Surface Segregation in Yttria Stabilised Zirconia”
Proc. 7th European Conference on Applications of Surface and Interface Analysis, ECASIA’97, Göteborg, 1997, Ed. I. Olefjord, L. Nyborg, D. Briggs, J. Wiley & Sons, Chichester, 1997, p. 255 – 258
11. J. Jedliński, A. Glazkov, M. Konopka, G. Borchardt, E. Tscherkasova, M. Bronfin, M. Nocun
“An XPS/SEM/EDX study of the early oxidation stages of Fe19Cr5Al (Y) alumina-forming alloys at 1173 K"
Applied Surface Science, 103, 205 – 216 (1996)

Additional information:

None