Module also offered within study programmes:
Code Study programme
CCE-2-319-MK-s Ceramics (Materiały dla konserwacji i rewitalizacji) - full-time studies second-cycle studies
CTC-2-319-TM-s Chemical Technology (Technologia materiałów budowlanych) - full-time studies second-cycle studies
CCE-2-319-CT-s Ceramics (Ceramika techniczna i konstrukcyjna) - full-time studies second-cycle studies
CTC-2-330-AK-s Chemical Technology (Analityka i kontrola jakości) - full-time studies second-cycle studies
CTC-2-419-AK-s Chemical Technology (Analityka i kontrola jakości) - full-time studies second-cycle studies
CCE-1-006-s Ceramics - full-time studies first-cycle studies
CIM-2-419-MF-s Materials Science (Materiały funkcjonalne) - full-time studies second-cycle studies
CCE-2-319-WC-s Ceramics (Wzornictwo ceramiki i szkła) - full-time studies second-cycle studies
CIM-2-319-FM-s Materials Science (Functional Materials) - full-time studies second-cycle studies
CIM-2-319-MF-s Materials Science (Materiały funkcjonalne) - full-time studies second-cycle studies
CIM-2-319-MN-s Materials Science (Zaawansowane Materiały Ceramiczne) - full-time studies second-cycle studies
CIM-2-319-BK-s Materials Science (Biomateriały i kompozyty) - full-time studies second-cycle studies
CTC-2-319-TC-s Chemical Technology (Technologia ceramiki i materiałów ogniotrwałych) - full-time studies second-cycle studies
CTC-2-319-TS-s Chemical Technology (Technologia szkła i powłok amorficznych) - full-time studies second-cycle studies
CIM-1-071-s Materials Science - full-time studies first-cycle studies
General information:
Name:
Experimental methods in solid state chemistry
Course of study:
2018/2019
Code:
CIM-2-319-BK-s
Faculty of:
Materials Science and Ceramics
Study level:
Second-cycle studies
Specialty:
Biomateriały i kompozyty
Field of study:
Materials Science
Semester:
3
Profile of education:
Academic (A)
Lecture language:
English
Form and type of study:
Full-time studies
Course homepage:
 
Responsible teacher:
dr inż. Prażuch Janusz (prazuch@agh.edu.pl)
Academic teachers:
dr inż. Prażuch Janusz (prazuch@agh.edu.pl)
Module summary

Description of learning outcomes for module
MLO code Student after module completion has the knowledge/ knows how to/is able to Connections with FLO Method of learning outcomes verification (form of completion)
Skills
M_U001 Students will gain information of methods of crystallography and diffraction: X-Ray (powder (XRD), single crystals), electron and neutron diffraction. Understanding and analysis of structural data acquired using diffraction methods from polycrystalline materials, texture analysis by a pole figure method will be discussed. IM2A_U06, IM2A_U07, IM2A_U01
M_U002 Students will gain information of classes of possible reactions of solid-state synthesis and routes of preparation of solids with the required properties. Basic knowledge of students concerning bonding in solids and structure and properties of solids. IM2A_U03, IM2A_U01
M_U003 Students will gain information of different microscopic and related techniques: reflected light microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) combined with chemical microanalysis (EDS and WDS), selected area diffraction (SAD) and their application for topography, morphology, microstructure, texture, particle size and shape, surface details, precipitations presence, chemical and structure analysis. IM2A_U06, IM2A_U02 Examination
M_U004 Students will gain information of the most frequently used surface analytical methods: AES, XPS, SIMS, SNMS, GDOES and also related spectroscopies like SEXAFS, EELS, and LEED regarding their application, possibilities and limitations. IM2A_U06 Test
M_U005 Students will gain information of experimental determining transport properties of solids; understanding the determined transport properties in relation to the nature of the bonding and the dynamical properties of the lattice, point defect and electronic structure. IM2A_U06, IM2A_U02, IM2A_U08 Test
M_U006 Students will gain information of measuring the magnetic properties of solids and obtaining chemical information from magnetic measurements (response of materials to magnetic fields). IM2A_U09, IM2A_U08 Test
M_U007 Students will gain a basic information of techniques of absorption, reflection, and emission of light and their application for characterization of solids. IM2A_U08 Test
M_U008 Students will gain a good knowledge of thermal analysis techniques: measurement of certain physical and chemical properties as a function of temperature (enthalpy, heat capacity, mass and coefficient of thermal expansion) using thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimetry (DSC), thermomechanical anlaysis (TMA). IM2A_U06, IM2A_U08 Test
M_U009 Students will be familiar with the selected methods important in the study of defects in solids, solid solutions and mechanisms of film growth and interpretation of their results. IM2A_U06, IM2A_U08
Knowledge
M_W001 Providing knowledge of types of solids and synthesis methods of solid-state materials. IM2A_W03, IM2A_W02 Examination
M_W002 Providing knowledge of diffraction methods for structure determination: X-ray, neutron, and electron diffraction. IM2A_U06, IM2A_U08 Test
M_W003 Providing knowledge of electron microscopy imaging and diffraction methods; scanning electron microscopy (SEM), transmission electron microscopy (TEM). Combination of electron imaging and chemical microanalysis (EDS and WDS); Electron microscopy sample preparation methods; Focused Ion Beam (FIB) technique. IM2A_W02, IM2A_W08 Examination
M_W004 Providing knowledge of surface analysis techniques; X-ray Photoelectron Spectroscopy (XPS), Auger Electron Spectroscopy (AES), Secondary Ion Mass Spectrometry (SIMS), Secondary Neutral Mass Spectrometry (SNMS), tracer methods, Rutheford Backscattering Analysis (RBS) and Glow Discharge Optical Emission Spectroscopy (GDOES), Surface Extended X-Ray Absorption Fine Structure (SEXAFS), Electron energy loss spectroscopy (EELS), Low-Energy Electron Diffraction (LEED). IM2A_W02, IM2A_W08 Test
M_W005 Providing knowledge of techniques of transport measurement of a solid material: d.c.conductivity (electrical resitivity), a.c. conductivity (impedance), thermopower, Hall effect, photoconductivity, thermal conductivity. Relation of the determined transport properties of solids with electronic structure. IM2A_W02, IM2A_W14, IM2A_W08, IM2A_W11 Examination
M_W006 Providing knowledge of magnetic measurements of materials and correletion of magnetic susceptibility with chemistry of substances. IM2A_W02, IM2A_W08 Examination
M_W007 Providing knowledge of optical techniques used for characterization of solids: absorption, reflectivity, and luminescence. IM2A_W02, IM2A_W08 Examination
M_W008 Providing knowledge of thermal analysis investigation methods: thermogravimetry (TG), differential thermal analysis (DTA), and differential scanning calorimetry (DSC). IM2A_W14, IM2A_W08 Examination
M_W009 Providing collective information on experimental methods for investigating defects in solids, solid solutions and film growth mechanisms. IM2A_W14, IM2A_W08 Examination
FLO matrix in relation to forms of classes
MLO code Student after module completion has the knowledge/ knows how to/is able to Form of classes
Lecture
Audit. classes
Lab. classes
Project classes
Conv. seminar
Seminar classes
Pract. classes
Zaj. terenowe
Zaj. warsztatowe
Others
E-learning
Skills
M_U001 Students will gain information of methods of crystallography and diffraction: X-Ray (powder (XRD), single crystals), electron and neutron diffraction. Understanding and analysis of structural data acquired using diffraction methods from polycrystalline materials, texture analysis by a pole figure method will be discussed. + - - - - - - - - - -
M_U002 Students will gain information of classes of possible reactions of solid-state synthesis and routes of preparation of solids with the required properties. Basic knowledge of students concerning bonding in solids and structure and properties of solids. + - - - - - - - - - -
M_U003 Students will gain information of different microscopic and related techniques: reflected light microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) combined with chemical microanalysis (EDS and WDS), selected area diffraction (SAD) and their application for topography, morphology, microstructure, texture, particle size and shape, surface details, precipitations presence, chemical and structure analysis. + - - - - + - - - - -
M_U004 Students will gain information of the most frequently used surface analytical methods: AES, XPS, SIMS, SNMS, GDOES and also related spectroscopies like SEXAFS, EELS, and LEED regarding their application, possibilities and limitations. + - - - - - - - - - -
M_U005 Students will gain information of experimental determining transport properties of solids; understanding the determined transport properties in relation to the nature of the bonding and the dynamical properties of the lattice, point defect and electronic structure. + - - - - + - - - - -
M_U006 Students will gain information of measuring the magnetic properties of solids and obtaining chemical information from magnetic measurements (response of materials to magnetic fields). - - - - - + - - - - -
M_U007 Students will gain a basic information of techniques of absorption, reflection, and emission of light and their application for characterization of solids. + - - - - + - - - - -
M_U008 Students will gain a good knowledge of thermal analysis techniques: measurement of certain physical and chemical properties as a function of temperature (enthalpy, heat capacity, mass and coefficient of thermal expansion) using thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimetry (DSC), thermomechanical anlaysis (TMA). + - - - - + - - - - -
M_U009 Students will be familiar with the selected methods important in the study of defects in solids, solid solutions and mechanisms of film growth and interpretation of their results. + - - - - + - - - - -
Knowledge
M_W001 Providing knowledge of types of solids and synthesis methods of solid-state materials. + - - - - - - - - - -
M_W002 Providing knowledge of diffraction methods for structure determination: X-ray, neutron, and electron diffraction. - - - - - - - - - - -
M_W003 Providing knowledge of electron microscopy imaging and diffraction methods; scanning electron microscopy (SEM), transmission electron microscopy (TEM). Combination of electron imaging and chemical microanalysis (EDS and WDS); Electron microscopy sample preparation methods; Focused Ion Beam (FIB) technique. + - - - - - - - - - -
M_W004 Providing knowledge of surface analysis techniques; X-ray Photoelectron Spectroscopy (XPS), Auger Electron Spectroscopy (AES), Secondary Ion Mass Spectrometry (SIMS), Secondary Neutral Mass Spectrometry (SNMS), tracer methods, Rutheford Backscattering Analysis (RBS) and Glow Discharge Optical Emission Spectroscopy (GDOES), Surface Extended X-Ray Absorption Fine Structure (SEXAFS), Electron energy loss spectroscopy (EELS), Low-Energy Electron Diffraction (LEED). + - - - - - - - - - -
M_W005 Providing knowledge of techniques of transport measurement of a solid material: d.c.conductivity (electrical resitivity), a.c. conductivity (impedance), thermopower, Hall effect, photoconductivity, thermal conductivity. Relation of the determined transport properties of solids with electronic structure. + - - - - - - - - - -
M_W006 Providing knowledge of magnetic measurements of materials and correletion of magnetic susceptibility with chemistry of substances. + - - - - - - - - - -
M_W007 Providing knowledge of optical techniques used for characterization of solids: absorption, reflectivity, and luminescence. + - - - - - - - - - -
M_W008 Providing knowledge of thermal analysis investigation methods: thermogravimetry (TG), differential thermal analysis (DTA), and differential scanning calorimetry (DSC). + - - - - - - - - - -
M_W009 Providing collective information on experimental methods for investigating defects in solids, solid solutions and film growth mechanisms. + - - - - - - - - - -
Module content
Lectures:
  1. Synthesis of solid-state materials.
  2. Diffraction methods.
  3. Electron microscopy.
  4. Transmission Electron Microscopy. TEM sample preparation. Visit to IC-EM.
  5. Surface and interface analysis methods.
  6. Magnetic measurements.
  7. Optical techniques.
  8. Thermal analysis.
Seminar classes:
  1. Electron microscopy techniques and sample preparation.
  2. Electrical resistance and impedance measurements.
  3. Magnetic and optical techniques.
  4. Thermogravimetry (TG) and Differential Thermal Analysis (DTA).
  5. Experimental methods for investigating defects in solids and solid solutions.
Student workload (ECTS credits balance)
Student activity form Student workload
Summary student workload 75 h
Module ECTS credits 3 ECTS
Examination or Final test 3 h
Contact hours 3 h
Realization of independently performed tasks 40 h
Participation in lectures 16 h
Participation in seminar classes 9 h
Participation in practical classes 2 h
Participation in study tours 2 h
Additional information
Method of calculating the final grade:

0,8 examination + 0,2 seminar activity.

Prerequisites and additional requirements:

Basic knowledge of physics and chemistry.

Recommended literature and teaching resources:

1. Basic solid state chemistry / A.R. West.-2nd ed., John Wiley & Sons Ltd.
2. Introduction to solid state physics, / Charles Kittel.-7th ed.
3. Surfaces and Interfaces of Solid Materials / Hans Luth.-3rd ed.
4. Structure of crystals / Boris K. Vainshtein et al.-2nd ed.
5. The science and engineering of materials / Donal R. Askeland
6. Impedance spectroscopy. Theory, Experiment, and Applications / Evgenij Barsoukov, J. Ross Macdonald, eds..-2nd ed.
7 Reactions and Characterization of Solids / Sandra E. Dann
8. Optical properties of solids. An introductory textbook / Locharoenrat Kitsakorn
9. Introduction to thermal analysis of solids. Techniques and Applications / Michael E. Brown.-2nd ed.
10. Thermal analysis of Materials / Robert. F. Speyer
11. Electron Microscopy and Analysis/ Peter j. Goodhew at al.-3rd ed.
12. Transmission electron microscopy. Physics of Image Formation and Analysis / Ludwig Reimer.-4th ed.
13. High temperature oxidation and corrosion of metals / David John Young.-2nd ed.
14.Introduction to texture analysis. Macrotexture, microtexture and orientation mapping / Olaf Engler, Valerie Randle.-2nd ed.
14. Focused Ion Beam Systems. Basics and Applictions / Yao Nan
15. Scanning electron microscopy and X-ray microanalysis / Joseph I. Goldstein, Dale Newbury et al.-3rd ed.
16. Transmission Electron Microscopy. A textbook for Materials Science / David B. Williams, C. Barry Carter.-2nd ed.
17. Electron Backscatter Diffraction in Materials Science / Adam J. Schwartz et al. /eds/
17.Texture and Anisotropy / U. F. Kocks
18. The Chemistry and Physics of Coatings / Alastair R. Marrion
19. The Chemistry and Physics of Coatings / Alastair R. Marrion
20. The basics of crystallography and diffraction / Christopher Hammond.-4th ed.
21. Introduction to disloctaions / Derek Hull.-5th ed.
22. Refractory and ceramic materials / Luis F. Verdeja, Jose P. Sancho et al.
23. Imperfections in crystalline solids/ Wei Cai, William D. Nix
24. Thermodynamics in Materials Science / Robert DeHoff.-2nd ed.
25. Diffusion in Solids / Paul G. Shewmon.-2nd ed.
26. Structure of Materials: An Introduction to Crystallography, Diffraction and Symmetry / Marc de Graef.-2nd ed.
27.Kinetics of materials / Robert W. Balluffi, Sam Allen, W.Craig Carter
28. Introduction to polymers / Robert J. Young
29. Phase transformations in metals and alloys / David A. Porter et al.
30. Materials Kinetics Fundamentals / Ryan O’Hayre

3. D.M. Adams, Inorganic Solids
4. A.K. Cheetham and P. Day, Solid State Chemistry : 1. Techniques and 2. Applications
5. P.A. Cox, The electronic structure and chemistry of solids
6. P.A. Cox, Transition metal oxides
7. R.C. Evans, An Introduction to crystal chemistry
8. A.F. Wells, Structural Inorganic Chemistry
9. N.N. Greenwood, Ionic crystal, lattice defect and non-stoichiometry
10. L. Smart and E. Moore, Solid state chemistry : An introduction
11. J.K. Burdett, Chemical bonding in solids
12. C.N.R. Rao and J. Gopalakrishnan, New directions in solid state chemistry
13. C.N.R. Rao, Chemical approaches to synthesis of inorganic materials

Scientific publications of module course instructors related to the topic of the module:

Additional scientific publications not specified

Additional information:

None